Functionalizing graphene by embedded boron clusters.

نویسندگان

  • Alexander Quandt
  • Cem Ozdoğan
  • Jens Kunstmann
  • Holger Fehske
چکیده

We present a model system that might serve as a blueprint for the controlled layout of graphene based nanodevices. The systems consists of chains of B(7) clusters implanted in a graphene matrix, where the boron clusters are not directly connected. We show that the graphene matrix easily accepts these alternating B(7)-C(6) chains and that the implanted boron components may dramatically modify the electronic properties of graphene based nanomaterials. This suggests a functionalization of graphene nanomaterials, where the semiconducting properties might be supplemented by parts of the graphene matrix itself, but the basic wiring will be provided by alternating chains of implanted boron clusters that connect these areas.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Spin-polarized transport through a zigzag-edge graphene flake embedded between two armchair nanoribbons electrodes

We study the coherent spin-polarized transport through a zigzag-edge graphene flake (ZGF), using Hubbard model in the nearest neighbor approximation within the framework of the Green function’s technique and Landauer formalism. The system considered consists of electrode/ (ZGF)/electrode, in which the electrodes are chosen to be armchair nanoribbons. The study was performed for two types of ele...

متن کامل

Oriented graphene nanoribbons embedded in hexagonal boron nitride trenches

Graphene nanoribbons (GNRs) are ultra-narrow strips of graphene that have the potential to be used in high-performance graphene-based semiconductor electronics. However, controlled growth of GNRs on dielectric substrates remains a challenge. Here, we report the successful growth of GNRs directly on hexagonal boron nitride substrates with smooth edges and controllable widths using chemical vapou...

متن کامل

Transport properties of graphene nanoroads in boron nitride sheets.

We demonstrate that the one-dimensional (1D) transport channels that appear in the gap when graphene nanoroads are embedded in boron nitride (BN) sheets are more robust when they are inserted at AB/BA grain boundaries. Our conclusions are based on ab initio electronic structure calculations for a variety of different crystal orientations and bonding arrangements at the BN/C interfaces. This pro...

متن کامل

Quantum Dots and Nanoroads of Graphene Embedded in Hexagonal Boron Nitride

T materials have drawn tremendous attention in the recent past in terms of both interesting fundamental physics and possible applications in future generation devices. Graphene and hexagonal boron nitride (h-BN) are the two most promising candidates for this purpose. 3 Single layers of graphene and h-BN have been fabricated and found to be stable at room temperature. 8 The most significant diff...

متن کامل

Wettability of boron monolayer using molecular dynamics simulation method

Over the past years, two-dimensional materials such as graphene, phosphorene, silicene, and boron-nitride have attracted the attention of many researchers. After the successful synthesis of graphene, due to its many new applications, researches began to produce nanosheets from other elements, and among these elements, boron was one of the options. In the periodic table of elements, boron is ahe...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Nanotechnology

دوره 19 33  شماره 

صفحات  -

تاریخ انتشار 2008